| 92 | 230 | A New Enemy! The Materialization of Zanpakutō |
| 93 | 231 | Byakuya, Disappearing with the Cherry Blossoms |
| 94 | 232 | Sode no Shirayuki vs. Rukia! Confused Heart |
| 95 | 233 | Zangetsu Becomes an Enemy |
| 96 | 234 | Renji Surprised?! The Two Zabimarus |
| 97 | 235 | Clash! Hisagi vs. Kazeshini |
| 98 | 236 | Release! The New Getsuga Tenshō |
| 99 | 237 | Suì-Fēng, Surrounding the Zanpakutō |
| 100 | 238 | Friendship? Hatred? Haineko & Tobiume |
| 101 | 239 | The Awakening Hyōrinmaru! Hitsugaya's Fierce Fight |
| 102 | 240 | Byakuya's Betrayal |
| 103 | 241 | For the Sake of Pride! Byakuya vs. Renji |
| 104 | 242 | Shinigami and Zanpakutō, Total Sortie |
| 105 | 243 | One-to-One Fight! Ichigo vs. Senbonzakura |
| 106 | 244 | The Long Awaited... Kenpachi Appears! |
| 107 | 245 | Pursue Byakuya! The Confused Gotei Divisions |
| 108 | 246 | Special Mission! Rescue Captain Commander Yamamoto! |
| 109 | 247 | Deceived Shinigami! The World Collapse Crisis |
| 110 | 248 | Dragon of Ice and Dragon of Flame! The Strongest Showdown! |
| 111 | 249 | Senbonzakura's Bankai! Offense and Defense of the Living World |
| 112 | 250 | That Man, for the Sake of the Kuchiki |
| 113 | 251 | Dark History! The Worst Shinigami Is Born |
| 114 | 252 | Byakuya, the Truth Behind His Betrayal |
| 115 | 253 | Muramasa's True Identity Revealed |
| 116 | 254 | Byakuya and Renji, the 6th Division Returns |
| 117 | 255 | Final Chapter - Zanpakutō The Alternate Tale |
| 118 | 256 | The Angered Byakuya! The Collapse of the Kuchiki House |
| 119 | 257 | A New Enemy! The True Nature of the Sword Fiends |
| 120 | 258 | Stray Snake, Tortured Monkey |
| 121 | 259 | Terror! The Monster That Lurks Underground |